Issue 2, 1986
From the journal:

Journal of the Chemical Society, Perkin Transactions 2

Quasi-template effect: a tool for controlling stereochemistry in acyclic systems. Attempted stereoselective synthesis of α,α′-dimethoxystilbene

Yoshihisa Inoue,   Hirokazu Ikeda  and  Tadao Hakushi  

Abstract

Alkylation with methyl tosylate of stilbenediol dianion, prepared in the reaction of benzoin with a series of alkali-metal hydroxides in THF, gave (E)- and (Z)-α,α′-dimethoxystilbenes as the major products in most cases, the E:Z ratio of which varies from 0.4 to 5.0 depending upon the alkali-metal cation employed; the results are rationalized in the quasi-template effect in an acyclic system and the hard–soft ion principle.

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Article information

DOI
https://doi.org/10.1039/P29860000259
Article type
Paper

J. Chem. Soc., Perkin Trans. 2, 1986, 259-262

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Quasi-template effect: a tool for controlling stereochemistry in acyclic systems. Attempted stereoselective synthesis of α,α′-dimethoxystilbene

Y. Inoue, H. Ikeda and T. Hakushi, J. Chem. Soc., Perkin Trans. 2, 1986, 259 DOI: 10.1039/P29860000259

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