The natural oestrogens, oestrone and oestradiol, are covalently bound to calf thymus deoxyribonucleic acid by the action of iodine and hydrogen peroxide. For oestrone, dual isotopic labelling indicates that these processes involve position 4 and/or 2 of the steroid.
G. M. Blackburn, B. Kellard, L. Orgee and M. H. Thompson, J. Chem. Soc., Perkin Trans. 2, 1985, 287 DOI: 10.1039/P29850000287
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