Issue 1, 1984
From the journal:

Journal of the Chemical Society, Perkin Transactions 2

An approach to the synthesis of dodecahedrane: the X-ray crystal structures of six intermediate compounds

Jack E. Baldwin,   Paul L. M. Beckwith,   John D. Wallis,   Anthony P. K. Orrell  and  Keith Prout  

Abstract

The X-ray crystal structures (0.03 < R < 0.06) of six compounds isolated during an approach to the synthesis of dodecahedrane are described. The highly substituted C13-tetraquinane (4) and the C19-heptaquinanetrione (6) are twisted out of mirror symmetry to minimise steric interactions. The bridged C19-hexaquinanetriones (7) and (8) and the C19-hexaquinanetriones (9) show signs of strain in the molecular skeleton and the doubly bridged C19-hexaquinanetrione (10) is even distorted showing both bond stretching and bond compression.

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Article information

DOI
https://doi.org/10.1039/P29840000053
Article type
Paper

J. Chem. Soc., Perkin Trans. 2, 1984, 53-61

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An approach to the synthesis of dodecahedrane: the X-ray crystal structures of six intermediate compounds

J. E. Baldwin, P. L. M. Beckwith, J. D. Wallis, A. P. K. Orrell and K. Prout, J. Chem. Soc., Perkin Trans. 2, 1984, 53 DOI: 10.1039/P29840000053

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