Issue 4, 1979
From the journal:

Journal of the Chemical Society, Perkin Transactions 2

On the crystal and molecular structure of 1,4-diphenylbuta-1,2,3-triene in connection with its stereospecific synthesis from (Z)-2-phenyl-1-(methylthio)vinyl cuprate and its conversion into (1Z,3E)-2-ethyl-1,4-diphenylbuta-1,3-diene

Wilbert G. M. van den Hoek,   Jan Kroon,   Henk Kleijn,   Hans Westmijze,   Peter Vermeer  and  Hendrick J. T. Bos  

Abstract

The crystal and molecular structure of the title compound (1) has been determined by single-crystal X-ray diffraction. Crystals are orthorhombic, space group Pcab, with cell dimensions a= 8.029(7), b= 13.032(6), c= 22.09(2)Å, and Z= 8. The structure was solved by direct methods and refined by block-diagonal least-squares to R 0.038 for 690 observed reflections. The molecular configuration is cis, which is of significance for establishing the stereochemistry of additions to the inner double bond. Parallel butatriene chains with a mean distance of 3.7 Å are stacked in planes parallel to (010).

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Article information

DOI
https://doi.org/10.1039/P29790000423
Article type
Paper

J. Chem. Soc., Perkin Trans. 2, 1979, 423-426

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On the crystal and molecular structure of 1,4-diphenylbuta-1,2,3-triene in connection with its stereospecific synthesis from (Z)-2-phenyl-1-(methylthio)vinyl cuprate and its conversion into (1Z,3E)-2-ethyl-1,4-diphenylbuta-1,3-diene

W. G. M. van den Hoek, J. Kroon, H. Kleijn, H. Westmijze, P. Vermeer and H. J. T. Bos, J. Chem. Soc., Perkin Trans. 2, 1979, 423 DOI: 10.1039/P29790000423

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