Barriers to rotation about the N–O bond in the hydroxylamine derivatives (4) have been found to be ca. 15 kcal mol–1. There is a sizeable contribution to these barriers from non-bonded interactions in the transition states.
F. G. Riddell and E. S. Turner, J. Chem. Soc., Perkin Trans. 2, 1978, 707 DOI: 10.1039/P29780000707
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