Issue 5, 1974
From the journal:

Journal of the Chemical Society, Perkin Transactions 2

Substituent effects in tautomerism. Part I. Acyl- and sulphonylamidines

Swee–Ong Chua,   Michael J. Cook  and  Alan R. Katritzky  

Abstract

The tautomerism of acyl- and sulphonyl-amidines is reviewed. The structures of the cations of mobile and fixed forms of acetyl-, benzoyl-, mesyl-, and tosyl-amidines are established by u.v. spectroscopy. Quantitative pKa measurements demonstrate that the H2N–CR[double bond, length half m-dash]N–Y form predominates for all series with KTca. 30 for the acyl- and ca. 107 for the sulphonyl compounds.

These results are compared with the tautomerism of 2-acylamino- and 2-sulphonamido-pyridines, and differences in tautomeric behaviour are rationalised.

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/P29740000546
Article type
Paper

J. Chem. Soc., Perkin Trans. 2, 1974, 546-552

Permissions

Request permissions

Substituent effects in tautomerism. Part I. Acyl- and sulphonylamidines

S. Chua, M. J. Cook and A. R. Katritzky, J. Chem. Soc., Perkin Trans. 2, 1974, 546 DOI: 10.1039/P29740000546

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements