Issue 4, 1996

Reactions of α-trimethylsilylvinyl carbanions with carboxylic acid derivatives: the relationship between product distribution and substrate reactivity

Abstract

The reaction between α-trimethylsilylvinyl carbanions and carboxylic acid derivatives gives α,β-unsaturated carbonyl compounds which, under the reaction conditions, undergo further conjugate addition. Further reactions can also occur, depending upon the reactivities of the enolates and of the carboxylic acid derivatives.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1996, 327-331

Reactions of α-trimethylsilylvinyl carbanions with carboxylic acid derivatives: the relationship between product distribution and substrate reactivity

A. R. Bassindale, I. Katampe, P. A. Kyle and P. G. Taylor, J. Chem. Soc., Perkin Trans. 1, 1996, 327 DOI: 10.1039/P19960000327

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