SCHEDULED MAINTENANCE
Regiospecific ring opening of (R)-(+)- or (S)-(–)-glycidol 1a, b with primary and secondary alcohols in the presence of diisobutylaluminium hydride provides 1-O-alkyl-sn-glycerol 2 without formation of the undesired regioisomer, 2-O-alkylglycerol 3. The configuration of the glycidol is preserved in the product.
R. K. Erukulla, H. Byun, D. C. Locke and R. Bittman, J. Chem. Soc., Perkin Trans. 1, 1995, 2199 DOI: 10.1039/P19950002199
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