SCHEDULED MAINTENANCE
Synthetic studies towards manzamine A are described. A tandem sulfolene SO2 extrusion intramolecular Diels–Alder cyclisation gave the C-5 epimer of the manzamine tricyclic ABC ring system via a C-5 to C-8 diene bearing a C-5/C-6 Z-alkene.
J. Leonard, S. P. Fearnley, M. R. Finlay, J. A. Knight and G. Wong, J. Chem. Soc., Perkin Trans. 1, 1994, 2359 DOI: 10.1039/P19940002359
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