Issue 0, 1983

Synthesis of L-serine stereospecifically labelled at C-3 with deuterium

Abstract

(2S,3R)-[3-2H1]- and (2S,3S)-[2,3-2H2]-Serines have been synthesised from the corresponding labelled aspartic acids. The synthesis involves a Baeyer-Villiger oxidation in which a migrating primary chiral centre rearranges with retention of stereochemistry.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1983, 2393-2398

Synthesis of L-serine stereospecifically labelled at C-3 with deuterium

D. Gani and D. W. Young, J. Chem. Soc., Perkin Trans. 1, 1983, 2393 DOI: 10.1039/P19830002393

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