Issue 0, 1983

Functionalisation of saturated hydrocarbons. Part 1. Some reactions of a ferrous chloride–chloramine-T complex with hydrocarbons

Abstract

The reactions of several hydrocarbon substrates with a ferrous chloride–chloramine-T complex, generated in situ, have been studied. Tosylamination of adamantane and chlorination of mesitylene proceed in good yield while naphthalene gives N,N′-bis(toluene-p-sulphonyl)-1,4-naphthoquinone di-imine. A variety of olefinic substrates undergo both cis- and trans-addition to the double bond as well as allylic functionalisation.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1983, 445-451

Functionalisation of saturated hydrocarbons. Part 1. Some reactions of a ferrous chloride–chloramine-T complex with hydrocarbons

D. H. R. Barton, R. S. Hay-Motherwell and W. B. Motherwell, J. Chem. Soc., Perkin Trans. 1, 1983, 445 DOI: 10.1039/P19830000445

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