Issue 0, 1979
From the journal:

Journal of the Chemical Society, Perkin Transactions 1

Heterocycles in organic synthesis. Part 25. Reagents for the conversion of halides into aldehydes and ketones

Alan R. Katritzky,   Michael J. Cook,   S. Bruce Brown,   Raymundo Cruz,   George H. Millet  and  Ali Anani  

Abstract

The sodium salts of 1-hydroxy-4,6-diphenyl-2-pyridone, 3-hydroxy-2-phenyl-4(3H)-quinazolinone, and 2-benzenesulphonamidopyridine 1-oxide react with alkyl and benzyl halides to give crystalline N-alkoxy- and N-benzyloxy-derivatives. The latter undergo thermolysis and photolysis to aromatic aldehydes and ketones in high yields. N-Alkoxy-analogues similarly yield aliphatic carbonyl compounds but these are contaminated by significant amounts of the corresponding alcohol.

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Article information

DOI
https://doi.org/10.1039/P19790002493
Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1979, 2493-2499

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Heterocycles in organic synthesis. Part 25. Reagents for the conversion of halides into aldehydes and ketones

A. R. Katritzky, M. J. Cook, S. B. Brown, R. Cruz, G. H. Millet and A. Anani, J. Chem. Soc., Perkin Trans. 1, 1979, 2493 DOI: 10.1039/P19790002493

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