Issue 0, 1972

Steroids and related studies. Part XIX. Products of the Schmidt reaction with cholest-4-ene-3,6-dione

Abstract

Treatment of cholest-4-ene-3,6-dione with an equimolar quantity of sodium azide in polyphosphoric acid yields 4-aza-A-homocholest-4a-ene-3,6-dione and 3-aza-A-homocholest-4a-ene-4,6-dione. The product obtained on treating 4-aza-A-homocholest-4a-ene-3,6-dione with 1 mol. equiv. of sodium azide or cholest-4-ene-3,6-dione with 2 mol. equiv. of sodium azide has been shown to be 4,6-diaza-AB-dihomocholest-4a-ene-3,7-dione.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1972, 993-994

Steroids and related studies. Part XIX. Products of the Schmidt reaction with cholest-4-ene-3,6-dione

H. Singh, S. Padmanabhan, A. K. Bose and I. Kugajevsky, J. Chem. Soc., Perkin Trans. 1, 1972, 993 DOI: 10.1039/P19720000993

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements