Issue 1, 1995
From the journal:

Journal of Materials Chemistry

Sol–gel synthesis of the magnetically frustrated oxides Sr2FeSbO6 and SrLaFeSnO6

Peter D. Battle,   Terence C. Gibb,   Andrew J. Herod  and  Jason P. Hodges  

Abstract

The use of the sol–gel synthesis method has been extended to include the preparation of stannates and antimonates from a citrate precursor. Samples of SrLaFeSnO6 and Sr2FeSbO6 have been prepared in a few hours. The structural and magnetic properties of the former are compared with those of a sample prepared over a period of several days by a solid-state route. The properties of Sr2FeSbO6 have been investigated by a combination of X-ray diffraction Mössbauer spectroscopy and SQUID magnetometry. The monoclinic perovskite structure has a partially (84%) ordered distribution of Fe and Sb cations over the six-coordinate sites; a transition to a magnetically frustrated phase occurs at 36 K.

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Article information

DOI
https://doi.org/10.1039/JM9950500075
Article type
Paper

J. Mater. Chem., 1995,5, 75-78

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Sol–gel synthesis of the magnetically frustrated oxides Sr2FeSbO6 and SrLaFeSnO6

P. D. Battle, T. C. Gibb, A. J. Herod and J. P. Hodges, J. Mater. Chem., 1995, 5, 75 DOI: 10.1039/JM9950500075

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