Issue 4, 1991
From the journal:

Journal of Materials Chemistry

Synthesis, structure and electrical properties of Sr2CuO2(CO3), an oxide carbonate related to perovskite

T. G. Narendra Babu,   Deborah J. Fish  and  Colin Greaves  

Abstract

The phase Sr2CuO2(CO3) occurs as an intermediate in the reaction between SrCO3 and CuO to form Sr2CuO3. The conditions of formation have been examined, and the structure determined from time-of-flight neutron powder diffraction [tetragonal, P4/mmm; a= 3.9033(2)Å, c= 7.4925(4)Å]. The structure consists of alternating layers of composition [CuO2]2– and [CO3]2– perpendicular to [001], separated by layers of Sr2+ cations. The carbonate groups are all oriented to have one C—O bond along [100] or [010], and two bonds at ca. 30° to [001]. No clear evidence for long-range ordering of the CO3 groups was found.

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/JM9910100677
Article type
Paper

J. Mater. Chem., 1991,1, 677-679

Permissions

Request permissions

Synthesis, structure and electrical properties of Sr2CuO2(CO3), an oxide carbonate related to perovskite

T. G. N. Babu, D. J. Fish and C. Greaves, J. Mater. Chem., 1991, 1, 677 DOI: 10.1039/JM9910100677

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements