Issue 1, 1992
From the journal:

Journal of Materials Chemistry

Structure of the cubic intercalate MgxTiS2

Philip Lightfoot,   Franciszek Krok,   Jan L. Nowinski  and  Peter G. Bruce  

Abstract

The structures of the intercalates MgxTiS2–c(0 < x < 0.25), prepared by chemical means, have been refined using high-resolution X-ray powder diffraction. The solid-solution adopts a structure derived from that of a spinel, with space group Fd3m. Magnesium exclusively occupies the octahedral 16c sites within the cubic close-packed sulfide array rather than the tetrahedral 8a sites, as would occur in a normal spinel. A linear increase of the cubic lattice parameter, a, and occupancy of the 16c site versus x is shown.

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Article information

DOI
https://doi.org/10.1039/JM9920200139
Article type
Paper

J. Mater. Chem., 1992,2, 139-140

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Structure of the cubic intercalate MgxTiS2

P. Lightfoot, F. Krok, J. L. Nowinski and P. G. Bruce, J. Mater. Chem., 1992, 2, 139 DOI: 10.1039/JM9920200139

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