SCHEDULED MAINTENANCE
The benzenesulphinate anion forms complexes with palladium(II) of the types [Pd(PhSO2)2(H2O)2], [PdX(PhSO2)2(H2O)]–, [PdX2(PhSO2)2]2–, [Pd(PhSO2)2L2], and [PdX(PhSO2)L2](X = anionic ligand, L = uncharged ligand). The ease of formation and the stability of the palladium–aquo-species indicates that the benzenesulphinato-ligand has a high trans-effect.
B. Chiswell and L. M. Venanzi, J. Chem. Soc. A, 1966, 1246 DOI: 10.1039/J19660001246
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