Issue 19, 1993
From the journal:

Journal of the Chemical Society, Faraday Transactions

Enthalpies of formation of buckminsterfullerene (C60) and of the parent ions C60+, C602+, C603+ and C60–

Hermínio P. Diogo,   Manuel E. Minas da Piedade,   T. John S. Dennis,   Jonathan P. Hare,   Harold W. Kroto,   Roger Taylor  and  David R. M. Walton  

Abstract

The standard enthalpy of formation of buckminsterfullerene (C60) in the crystalline state has been determined as 2278.1 ± 14.4 kJ mol–1 using a microcombustion calorimeter. Statistical mechanical calculations of the heat capacity of gaseous C60 as a function of the temperature and a critical survey of the literature data for the enthalpy of sublimation, the heat capacity in the crystalline state, the first, second and third ionization energies and the electron affinity of C60, enabled the enthalpy of formation of gaseous C60 and the enthalpies of formation of the ions C60+, C602+, C603+ and C60– to be derived.

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Article information

DOI
https://doi.org/10.1039/FT9938903541
Article type
Paper

J. Chem. Soc., Faraday Trans., 1993,89, 3541-3544

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Enthalpies of formation of buckminsterfullerene (C60) and of the parent ions C60+, C602+, C603+ and C60–

H. P. Diogo, M. E. M. da Piedade, T. J. S. Dennis, J. P. Hare, H. W. Kroto, R. Taylor and D. R. M. Walton, J. Chem. Soc., Faraday Trans., 1993, 89, 3541 DOI: 10.1039/FT9938903541

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