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P Spin–rotation hyperfine splitting has been observed in the 101â†�000 transitions of CH2![[double bond, length as m-dash]](https://www.rsc.org/images/entities/char_e001.gif)
P35Cl and CH2P37Cl by pulsed-nozzle, FT microwave spectroscopy. The transient molecules CH2PCl were produced by using a pyrolysis nozzle and then isolated on the ca. 10 µs timescale.
A. C. Legon and D. Stephenson, J. Chem. Soc., Faraday Trans., 1991, 87, 3325 DOI: 10.1039/FT9918703325
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