Issue 8, 1982
From the journal:

Journal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics

Time-resolved measurements of rotational energy transfer within the Ã2A1 state of NH2

Stephen J. Dearden,   Richard N. Dixon  and  David Field  

Abstract

Time- and energy-resolved spectroscopy of the laser-induced fluorescence of à state NH2 has allowed us to follow the evolution of the rotational population distribution when pumping in a single rovibronic transition. The primary scattering process shows an almost exclusive propensity for inelastic transitions with |ΔN|⩽2. The non-exponential decay observed in many experiments has been interpreted as arising from reversible transfer between fluorescent levels of the Ã, 2A1 state and high close-lying levels of the X, 2B1 ground state.

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Article information

DOI
https://doi.org/10.1039/F29827801423
Article type
Paper

J. Chem. Soc., Faraday Trans. 2, 1982,78, 1423-1432

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Time-resolved measurements of rotational energy transfer within the Ã2A1 state of NH2

S. J. Dearden, R. N. Dixon and D. Field, J. Chem. Soc., Faraday Trans. 2, 1982, 78, 1423 DOI: 10.1039/F29827801423

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