Issue 1, 1977
From the journal:

Journal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics

Characterization of the ground ionic state of the NS molecule using photoelectron spectroscopy

John M. Dyke,   Alan Morris  and  Ian R. Trickle  

Abstract

The band associated with the first ionization potential of the NS molecule, corresponding to the ionization NS+(X1Σ+)â†� NS(X2Π), has been observed by photoelectron spectroscopy using HeI and NeI photon sources. The vertical ionization potential of this process is measured as 8.87 eV, in good agreement with values predicted from ab initioΔSCF calculations. Vibrational structure associated with the observed band allows we and re to be estimated as (1415 ± 20) cm–1 and (1.440 ± 0.005)Å respectively for the NS+(X1Σ+) state.

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Article information

DOI
https://doi.org/10.1039/F29777300147
Article type
Paper

J. Chem. Soc., Faraday Trans. 2, 1977,73, 147-151

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Characterization of the ground ionic state of the NS molecule using photoelectron spectroscopy

J. M. Dyke, A. Morris and I. R. Trickle, J. Chem. Soc., Faraday Trans. 2, 1977, 73, 147 DOI: 10.1039/F29777300147

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