Issue 23, 1995
From the journal:

Journal of the Chemical Society, Dalton Transactions

Synthesis and characterization of new dimeric aminoalanes

Thomas Belgardt,   Jens Storre,   Andreas Klemp,   Heinz Gornitzka,   Ludger Häming,   Hans-Georg Schmidt  and  Herbert W. Roesky  

Abstract

The dimeric aminoalanes [Me2AlN(C6H11)2]21, (Me2AlNBui2)22, [(2,4,6-Me3C6H2)2AlNH2]24, [Cl2AlN(C6H11)2]25, (Me2AlNHCH2C5H4N-2)26 and the ammonia adduct (2,4,6-Me3C6H2)3Al·NH33 have been prepared by the reaction of substituted alanes with different amines. They have been fully characterized by elemental analyses, IR, NMR and mass spectrometry. The crystal structures of 1, 5 and 6 have been determined. Those of 1 and 6 display slightly folded four-membered rings with alternating aluminium and nitrogen atoms, while 5 consists of a square-planar Al2N2 ring system.

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Article information

DOI
https://doi.org/10.1039/DT9950003747
Article type
Paper

J. Chem. Soc., Dalton Trans., 1995, 3747-3751

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Synthesis and characterization of new dimeric aminoalanes

T. Belgardt, J. Storre, A. Klemp, H. Gornitzka, L. Häming, H. Schmidt and H. W. Roesky, J. Chem. Soc., Dalton Trans., 1995, 3747 DOI: 10.1039/DT9950003747

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