Issue 3, 1995

Dalton communications. A zwitterionic cluster compound: synthesis and characterisation of the triphenylphosphoniocyclo-pentadienide derivative [Ru6C(CO)145-C5H4PPh3)]

Abstract

The crystal and molecular structure of the zwitterionic octahedral cluster, [Ru6C(CO)145-C5H4PPh3)], prepared from the reaction of [Ru6C(CO)17] with trimethylamine N-oxide in the presence of triphenylphosphoniocyclopentadienide, has been established by low-temperature single-crystal X-ray diffraction analysis, and shows intermolecular interactions typical of zwitterionic compounds.

Article information

Article type
Paper

J. Chem. Soc., Dalton Trans., 1995, 495-496

Dalton communications. A zwitterionic cluster compound: synthesis and characterisation of the triphenylphosphoniocyclo-pentadienide derivative [Ru6C(CO)145-C5H4PPh3)]

A. J. Blake, B. F. G. Johnson, S. Parsons and D. S. Shephard, J. Chem. Soc., Dalton Trans., 1995, 495 DOI: 10.1039/DT9950000495

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