Issue 6, 1991
From the journal:

Journal of the Chemical Society, Dalton Transactions

Aluminium complexes of N,N′-ethylenebis(salicylideneimine)(H2salen). X-Ray crystal structures of [{Al(salen)}2(µ-O)]·MeCN and [Al(OC6H2Me3-2,4,6)(salen)]

Patrick L. Gurian,   Linda K. Cheatham,   Joseph W. Ziller  and  Andrew R. Barron  

Abstract

The reaction of AlMe3 with H2salen [N,N′-ethylenenbis(salicylideneimine)] in MeCN gives the five-co-ordinate aluminium complex [AlMe(salen)]1. The interaction of 1 with H2O, HOPh, HOC6H4But-4, HOC6H2Me3-2,4,6, HO2CMe, HO2CPh, acetylacetone and 2-HOC6H4C(O)Me has been studied, and the X-ray structures of two of the products [{Al(salen)}2(µ-O)]·MeCN and [Al(OC6H2Me3-2,4,6)(salen)] have been determined. The proton and 27Al-{1H} NMR and IR spectra of the compounds have been recorded.

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Article information

DOI
https://doi.org/10.1039/DT9910001449
Article type
Paper

J. Chem. Soc., Dalton Trans., 1991, 1449-1456

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Aluminium complexes of N,N′-ethylenebis(salicylideneimine)(H2salen). X-Ray crystal structures of [{Al(salen)}2(µ-O)]·MeCN and [Al(OC6H2Me3-2,4,6)(salen)]

P. L. Gurian, L. K. Cheatham, J. W. Ziller and A. R. Barron, J. Chem. Soc., Dalton Trans., 1991, 1449 DOI: 10.1039/DT9910001449

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