Issue 11, 1987
From the journal:

Journal of the Chemical Society, Dalton Transactions

Isometallocenes. Part 1. Polymethylated isocobaltocenium salts; a general route to [Co(C4Me4)(arene)]

Malcolm R. Cook,   Peter Härter,   Peter L. Pauson  and  Ján Šraga  

Abstract

The formation of tricarbonyl(tetramethylcyclobutadiene)cobalt hexafluorophosphate and its conversion into the neutral complexes [{Co(CO)2(C4Me4)}2] and [Co(CO)2(C4Me4)I] are described. Reaction of the latter with arenes in the presence of aluminium chloride provides a general route to the cations [Co(C4Me4)(arene)]+ of which seven new examples are described. Some carbonyl substitutions of the cation [Co(CO)3(C4Me4)]+ are also reported.

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/DT9870002757
Article type
Paper

J. Chem. Soc., Dalton Trans., 1987, 2757-2760

Permissions

Request permissions

Isometallocenes. Part 1. Polymethylated isocobaltocenium salts; a general route to [Co(C4Me4)(arene)]

M. R. Cook, P. Härter, P. L. Pauson and J. Šraga, J. Chem. Soc., Dalton Trans., 1987, 2757 DOI: 10.1039/DT9870002757

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements