Issue 6, 1979
From the journal:

Journal of the Chemical Society, Dalton Transactions

Synthesis of cationic pentacarbonyl, fac- and mer-tricarbonyl, and cis-and trans-dicarbonyl complexes of manganese(I)

Rafael Usón,   Victor Riera,   José Gimeno,   Mariano Laguna  and  M. Pilar Gamasa  

Abstract

The complexes [Mn(CO)5(OClO3)] and fac-[Mn(CO)3(OCMe2)3][ClO4] obtained by the reaction of [Mn(CO)5Br] with Ag[ClO4] in dichloromethane or acetone solution are suitable precursors for the synthesis of cationic complexes of the type [Mn(CO)5L][ClO4] and of the types fac-[Mn(CO)3L3][ClO4] and cis-[Mn(CO)2L4][ClO4](L = a Group 5B ligand) which, when L is a strong π acceptor, isomerize under reflux to mer-[Mn(CO)3L3][ClO4] or, respectively, to trans-[Mn(CO)2L4][ClO4].

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/DT9790000996
Article type
Paper

J. Chem. Soc., Dalton Trans., 1979, 996-1002

Permissions

Request permissions

Synthesis of cationic pentacarbonyl, fac- and mer-tricarbonyl, and cis-and trans-dicarbonyl complexes of manganese(I)

R. Usón, V. Riera, J. Gimeno, M. Laguna and M. P. Gamasa, J. Chem. Soc., Dalton Trans., 1979, 996 DOI: 10.1039/DT9790000996

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements