Issue 9, 1973

Confirmation of the non-existence of polymeric species in aqueous perchloric acid solutions of the hexa-aquocobalt(III) ion

Abstract

The use of AgI as a potential mediator in potentiometric measurements of the CoIII–CoII couple in aqueous perchloric acid solutions of the hexa-aquocobalt(III) ion does not invalidate the conclusion that the cobalt(III) species present are monomeric and behave as one-equivalent oxidants. Evidence from isotope distribution and kinetic studies is reviewed and shown to support this conclusion.

Article information

Article type
Paper

J. Chem. Soc., Dalton Trans., 1973, 900-902

Confirmation of the non-existence of polymeric species in aqueous perchloric acid solutions of the hexa-aquocobalt(III) ion

G. Davies and B. Warnqvist, J. Chem. Soc., Dalton Trans., 1973, 900 DOI: 10.1039/DT9730000900

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