Volume 56, 1973

Spectro-electrochemical methods in the study of short-lived intermediates

Abstract

The theoretical and experimental state of the art of spectro-electrochemistry as directed toward the study of short-lived intermediates is discussed. Particular emphasis is placed on the detection, characterization and kinetic monitoring of reactive intermediates during potential pulse and relaxation periods. Nucleophilic addition to radical dations with digital simulation of the possible mechanisms for the pulse-relaxation are presented using the thianthrene system as a working model.

Article information

Article type
Paper

Faraday Discuss. Chem. Soc., 1973,56, 16-27

Spectro-electrochemical methods in the study of short-lived intermediates

R. F. Broman, W. R. Heineman and T. Kuwana, Faraday Discuss. Chem. Soc., 1973, 56, 16 DOI: 10.1039/DC9735600016

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