Issue 14, 1996
From the journal:

Journal of the Chemical Society, Dalton Transactions

Copper(II) and cobalt(II) complexes of methyl 2-pyridyl ketone thiosemicarbazone (HL); single-crystal structure of [Cu(HL)L]NCS

Pilar Souza,   Ana I. Matesanz  and  Vicente Fernández  

Abstract

The complexes [M(HL)L]ClO4(HL = methyl 2-pyridyl ketone thiosemicarbazone; M = Cu 1 or Co 2) have been prepared from the reaction of HL with the appropriate perchlorate salt; [Cu(HL)L]NCS 3 was also prepared by transmetallation of [Pb2(HL)L(NCS)2]NCS with an excess of copper(II) perchlorate. The new complexes have been characterized by spectroscopic techniques and the crystal structure of 3 has been determined: green triclinic crystal, a= 10.150(2), b= 10.350(2), c= 11.890(2)Å, α= 88.55(3), β= 83.28(3), γ= 63.26(3)°, space group P[1 with combining macron], Z= 2. The copper atom is six-co-ordinated by two NNS donor sets from terdentate ligands.

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Article information

DOI
https://doi.org/10.1039/DT9960003011
Article type
Paper

J. Chem. Soc., Dalton Trans., 1996, 3011-3013

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Copper(II) and cobalt(II) complexes of methyl 2-pyridyl ketone thiosemicarbazone (HL); single-crystal structure of [Cu(HL)L]NCS

P. Souza, A. I. Matesanz and V. Fernández, J. Chem. Soc., Dalton Trans., 1996, 3011 DOI: 10.1039/DT9960003011

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