Dalton communications. Synthesis and characterization of [Li(OEt2)3][Co2(SC6H2Pri3-2,4,6)5]: a compound with a face-sharing ditetrahedral structure
Abstract
The reaction of Li(SC6H2Pri3-2,4,6) with CoCl2 in diethyl ether solution affords [Li(OEt2)3][Co2(SC6H2Pri3-2,4,6)5] which features an anion that has a unique face-sharing structure composed of two CoS4 tetrahedra.