Issue 13, 1992
From the journal:

Journal of the Chemical Society, Dalton Transactions

Thermodynamic study of dimethyltin(IV) complexes with nucleoside 5′-triphosphates

Giuseppe Arena,   Rosario Cali,   Annalinda Contino,   Nunzia Loretta,   Salvatore Musumeci  and  Roberto Purrello  

Abstract

The complex formation of [SnMe2]2+ ion with guanosine 5′-triphosphate (GTP), inosine 5′-triphosphate (ITP), cytidine 5′-triphosphate (CTP) and tripolyphosphate(5–)(tpp) has been investigated by means of potentiometric and calorimetric measurements at 25 °C and I= 0.1 mol dm–3(KNO3). On the basis of the thermodynamic parameters, bonding details have been inferred for the main nucleotide complex species, using tpp as reference. The thermodynamic data show that the nitrogen atom [N(1)] of the bases interacts with dimethyltin in the [SnMe2L] species of GTP and ITP only.

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Article information

DOI
https://doi.org/10.1039/DT9920002039
Article type
Paper

J. Chem. Soc., Dalton Trans., 1992, 2039-2043

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Thermodynamic study of dimethyltin(IV) complexes with nucleoside 5′-triphosphates

G. Arena, R. Cali, A. Contino, N. Loretta, S. Musumeci and R. Purrello, J. Chem. Soc., Dalton Trans., 1992, 2039 DOI: 10.1039/DT9920002039

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