Issue 4, 1984
From the journal:

Journal of the Chemical Society, Dalton Transactions

Synthesis of alkali-metal diaquafluoro-oxoperoxovanadate(IV) complexes [VO(O2)F(H2O)2]–

Mihir K. Chaudhuri  and  Soumitra K. Ghosh  

Abstract

Orange-red alkali metal diaquafluoro-oxoperoxovanadates(IV), A[VO(O2)F(H2O)2](A = NH4, K, Rb, or Cs), have been synthesised by the reaction of A[VOF4] with H2O2 in the molar ratio 1 : 12 followed by precipitation with ethanol. Characterisation of the compounds was made from the results of chemical analyses, chemical determination of oxidation state of vanadium, i.r. and electronic spectroscopic studies, and magnetic susceptibility measurements. I.r. spectra suggest that the peroxo-ligand is bonded to the V4+ centre in a triangular bidentate fashion.

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Article information

DOI
https://doi.org/10.1039/DT9840000507
Article type
Paper

J. Chem. Soc., Dalton Trans., 1984, 507-509

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Synthesis of alkali-metal diaquafluoro-oxoperoxovanadate(IV) complexes [VO(O2)F(H2O)2]–

M. K. Chaudhuri and S. K. Ghosh, J. Chem. Soc., Dalton Trans., 1984, 507 DOI: 10.1039/DT9840000507

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