Issue 27, 2023
From the journal:

Chemical Communications

Porous zeolitic imidazolate frameworks assembled with highly-flattened tetrahedral copper(ii) centres and 2-nitroimidazolates†

Cheolwon Jung,a   Sang Beom Choi,b   Jaewoo Park,c   Minji Jung,c   Jonghoon Kim, ORCID logo b   Hyunchul Oh ORCID logo *cd  and  Jaheon Kim ORCID logo *a  

* Corresponding authors

a Department of Chemistry, Soongsil University, Seoul, Republic of Korea
E-mail: jaheon@ssu.ac.kr

b Department of Physics and Integrative Institute of Basic Sciences, Soongsil University, Seoul, Republic of Korea

c Department of Chemistry, Ulsan National Institute of Science and Technology, Ulsan, Republic of Korea
E-mail: hcoh@unist.ac.kr

d Graduate School of Carbon Neutrality, Ulsan National Institute of Science and Technology, Ulsan, Republic of Korea

Abstract

Cu(II)-based zeolitic imidazolates (Cu-ZIFs), Cu-ZIF-gis and -rho, formulated as Cu(nIm)2 (nIm = 2-nitroimidazolate) have highly-flattened tetrahedral coordination geometry. Cu-ZIF-gis has 2.4 Å cylindrical pores that can adsorb H2 gas, and Cu-ZIF-rho has 19.8 Å cages with a BET surface area of 1320 m2 g−1.

Graphical abstract: Porous zeolitic imidazolate frameworks assembled with highly-flattened tetrahedral copper(ii) centres and 2-nitroimidazolates

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Article information

DOI
https://doi.org/10.1039/D2CC06797H
Article type
Communication
Submitted
14 Dec 2022
Accepted
06 Mar 2023
First published
07 Mar 2023

Chem. Commun., 2023,59, 4040-4043

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Porous zeolitic imidazolate frameworks assembled with highly-flattened tetrahedral copper(II) centres and 2-nitroimidazolates

C. Jung, S. B. Choi, J. Park, M. Jung, J. Kim, H. Oh and J. Kim, Chem. Commun., 2023, 59, 4040 DOI: 10.1039/D2CC06797H

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