Issue 29, 2022
From the journal:

Chemical Communications

An emerging deep eutectic solvent based on halogen-bonds†

Ruifen Shi,a   Dongkun Yu,a   Fengyi Zhou,a   Jiangfeng Yua  and  Tiancheng Mu ORCID logo *a  

* Corresponding authors

a Department of Chemistry, Renmin University of China, Beijing 100872, China
E-mail: tcmu@ruc.edu.cn
Tel: +86-10-62514925

Abstract

A new deep eutectic solvent (DES) driven by halogen bonding (XB) was exploited. A family of eutectic mixtures in the liquid state was obtained by the combination of quaternary ammonium salts and dihalogens. The formation mechanism was discussed based on experiments and DFT calculations. It not only broadens the potential DES systems but unlocks the possibility of XB complexes as solvents.

Graphical abstract: An emerging deep eutectic solvent based on halogen-bonds

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Article information

DOI
https://doi.org/10.1039/D2CC00528J
Article type
Communication
Submitted
26 Jan 2022
Accepted
10 Mar 2022
First published
10 Mar 2022

Chem. Commun., 2022,58, 4607-4610

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An emerging deep eutectic solvent based on halogen-bonds

R. Shi, D. Yu, F. Zhou, J. Yu and T. Mu, Chem. Commun., 2022, 58, 4607 DOI: 10.1039/D2CC00528J

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