The properties of inorganic nanoparticles (NPs) are governed by their size. Therefore, tuning the size of NPs is a fundamental technique in nanoscience. However, the size-tunable synthesis of inorganic NPs is generally carried out in a dilute solution, which produces large quantities of waste. Herein, we report the predictable size-tunable synthesis of Fe₃O₄ NPs by the stepwise thermal decomposition of iron(II) oxalate (Fe(ox)). Monodisperse Fe₃O₄ seed crystals were synthesized by the thermal decomposition of oleylamine-coordinated iron oxalate (Fe(ox)-OAm) in a small amount of oleylamine, followed by continuous seed-mediated growth of Fe₃O₄ NPs. The thermal decomposition behavior of Fe(ox) in oleylamine with and without N,N-diethyl-1,3-diaminopropane (dedap) revealed the important role of dedap in the stepwise thermal decomposition of Fe(ox). The size of the Fe₃O₄ NPs was easily tuned via the stepwise thermal decomposition of Fe(ox) by controlling the amount of decomposed Fe(ox) in a small amount of an alkylamine mixture. The particle diameter was predicted from the size of the Fe₃O₄ seed crystals and the amount of decomposed Fe(ox). Finally, the size dependency of magnetic properties of the synthesized Fe₃O₄ NPs was studied. This continuous seed-mediated growth method based on the stepwise thermal decomposition of metal oxalate can be applied to control the size of a variety of metal and metal oxide NPs.