Rechargeable aqueous zinc-ion batteries possess the merits of good environmental benignity, high operational safety and high energy density. Nevertheless, the practical application of zinc-ion batteries is severely obstructed by the inhomogeneous deposition of metallic Zn on the anode, which results in serious capacity fading, poor coulombic efficiency, and electrolyte consumption. Herein, we propose a simple strategy of constructing a functional nitrogen-doped carbon network coating layer on zinc foil for dendrite-free Zn stripping/plating. On one hand, the good conductivity of the artificial Zn/electrolyte interface can quickly balance the electric field and lower the nucleation overpotential. On the other hand, the porosity feature and functional groups of the protective layer can provide a fast Zn²⁺ transportation pathway and generate well-dispersed nucleation seeds. Therefore, the protective layer can effectively hamper the growth of metallic Zn dendrites and resist side reactions. The as-prepared N–C/Zn anode displays superior cycling stability (800 h at 2 mA cm⁻² with the capacity of 2 mA h cm⁻²) and a satisfactory coulombic efficiency of 98.76% during the Zn stripping/plating process. A long cycle life and high specific capacity (162.10 mA h g⁻¹ after 500 cycles at 2.0 A g⁻¹) are also obtained for N–C/Zn||ZnSO₄||V₂O₅ full cells. The strategy provides a facile and effective opportunity for constructing high-performance rechargeable aqueous zinc-ion batteries.