SCHEDULED MAINTENANCE
The synthesis of an optically active, 1,1′-binaphtyl-derived cyclophane receptor with a preorganized central cavity lined with four anionic phosphodiester groups for ionic hydrogen bonding is described. In competitive protic solvent mixtures, this receptor forms stable 1:1 complexes with disaccharides whereas the smaller monosaccharides are not significantly bound.
U. Neidlein and F. Diederich, Chem. Commun., 1996, 1493 DOI: 10.1039/CC9960001493
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