SCHEDULED MAINTENANCE
trans- or cis-β-Trimethylsilylvinyloxiranes are prepared by the reaction of aldehydes with a 3-trimethylsilylated dimethylsulfonium allylide under phase-transfer conditions or with a preformed 3-trimethylsilylated diphenylsulfonium allylide in the presence of LiBr, both in excellent yields and high stereoselectivity.
Y. Zhou, A. Li, X. Hou and L. Dai, Chem. Commun., 1996, 1353 DOI: 10.1039/CC9960001353
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