The reaction of molecular oxygen with 1-amino-diphosphene produces a novel 1,3-dioxo-2λ5, 4λ3, 5λ3-triphospholane-2-oxide via the [2 + 3]-addition of 2,4,6-tri-tert-butylphenylmetaphosphonate to the diphosphene monoxide, the structure of which is elucidated by X-ray analysis.
B. Kramer, E. Niecke, M. Nieger and R. W. Reed, Chem. Commun., 1996, 513 DOI: 10.1039/CC9960000513
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