A high-performance, highly bendable quasi-solid-state zinc–organic battery enabled by intelligent proton-self-buffering copolymer cathodes†
b
and
Dingshan
Yu
*a
Abstract
Herein, we report the first prototype of a highly bendable, quasi-solid-state Zn–poly(aniline-co-azure C) (PANAC) battery. The conformal assembly of the PANAC copolymer onto a porous carbon-sheathed carbon cloth was explored as a cathode, rendering the rich protonated nitrogen at a charged state and unique “proton-self-supplier” to drastically boost the polymer electroactivity in near-neutral aqueous electrolytes while enabling rapid electron/ion transport. This strategy harnesses the smart “proton-self-regulation” capability of a phenothiazine derivative in PANAC to surmount a long-standing conflict that the high electroactivity of the traditional polyaniline cathode demands a highly acidic environment, which is incompatible with Zn anodes. Thus, the aqueous Zn–PANAC cell delivers an impressive capacity and energy density of 306.3 mA h g−1 and 352.3 W h kg−1, respectively, – the highest values among the current zinc–polymer cells. The quasi-solid-state cell also yields a high capacity and energy density of 241.4 mA h g−1 and 289.3 W h kg−1, respectively, with a long lifespan (over 1000 cycles), and functions well when being bent, twisted, punctured and sewn.
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