Metal–organic conjugated microporous polymer containing a carbon dioxide reduction electrocatalyst

Charlotte L. Smith; Rob Clowes; Reiner Sebastian Sprick; Andrew I. Cooper; Alexander J. Cowan

doi:10.1039/C9SE00450E

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Metal–organic conjugated microporous polymer containing a carbon dioxide reduction electrocatalyst†

Charlotte L. Smith,^ab Rob Clowes,^a Reiner Sebastian Sprick,

^a Andrew I. Cooper

^a and Alexander J. Cowan

*^ab

Author affiliations

* Corresponding authors

^a Department of Chemistry and Materials Innovation Factory, University of Liverpool, Crown Street, Liverpool L69 7ZD, UK
E-mail: acowan@liverpool.ac.uk

^b Stephenson Institute for Renewable Energy, University of Liverpool, Peach Street, Liverpool, UK

Abstract

A metal–organic conjugated micorporous polymer (CMP) containing a manganese carbonyl electrocatalyst for CO₂ reduction has been synthesised and electrochemically characterised. Incorporation in a rigid framework changes the behavior of the catalyst, preventing reductive dimerization. These initial studies demonstrate the feasibility of CMP electrodes that can provide both high local CO₂ concentrations and well defined electrocatalytic sites.

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Article information

DOI: https://doi.org/10.1039/C9SE00450E
Article type: Communication
Submitted: 05 Jul 2019
Accepted: 08 Sep 2019
First published: 09 Sep 2019

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Sustainable Energy Fuels, 2019,3, 2990-2994

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Metal–organic conjugated microporous polymer containing a carbon dioxide reduction electrocatalyst

C. L. Smith, R. Clowes, R. S. Sprick, A. I. Cooper and A. J. Cowan, Sustainable Energy Fuels, 2019, 3, 2990 DOI: 10.1039/C9SE00450E

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Sustainable Energy & Fuels

Metal–organic conjugated microporous polymer containing a carbon dioxide reduction electrocatalyst†

Abstract

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Metal–organic conjugated microporous polymer containing a carbon dioxide reduction electrocatalyst

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