Issue 88, 2019

Revisiting the water sorption isotherm of MOF using electrical measurements

Abstract

Water adsorption/desorption isotherms of Cr-soc-MOF-1 were monitored electrically, with the translation of proton conductivity measurements to physisorption isotherms in terms of S-shape and hysteresis features revealed by volumetry. Molecular modelling further established the relationship between the evolutive water–hydrogen bonded network and the “electrical” isotherm for this water-mediated proton conducting MOF.

Graphical abstract: Revisiting the water sorption isotherm of MOF using electrical measurements

Supplementary files

Article information

Article type
Communication
Submitted
02 Aug 2019
Accepted
09 Oct 2019
First published
09 Oct 2019

Chem. Commun., 2019,55, 13251-13254

Revisiting the water sorption isotherm of MOF using electrical measurements

S. Nandi, H. Aggarwal, M. Wahiduzzaman, Y. Belmabkhout, G. Maurin, M. Eddaoudi and S. Devautour-Vinot, Chem. Commun., 2019, 55, 13251 DOI: 10.1039/C9CC06012J

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