Issue 54, 2019
From the journal:

Chemical Communications

Electrochemically stimulated molecule release associated with interfacial pH changes†

Madhura Bellare,‡a   Vasantha Krishna Kadambar,‡a   Paolo Bollella,a   Evgeny Katz*a  and  Artem Melman ORCID logo *a  

* Corresponding authors

a Department of Chemistry and Biomolecular Science, Clarkson University, Potsdam, NY 13699, USA
E-mail: amelman@clarkson.edu, ekatz@clarkson.edu

Abstract

A new linker with a hydrolyzable aryl ester bond was used for electrode modification. Basic pH locally produced at the electrode surface upon electrochemical reduction of O2 resulted in the hydrolytic cleavage of the aryl ester bond and release of the immobilized fluorescent dye used as a model compound.

Graphical abstract: Electrochemically stimulated molecule release associated with interfacial pH changes

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Article information

DOI
https://doi.org/10.1039/C9CC03467F
Article type
Communication
Submitted
05 May 2019
Accepted
12 Jun 2019
First published
12 Jun 2019

Chem. Commun., 2019,55, 7856-7859

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Electrochemically stimulated molecule release associated with interfacial pH changes

M. Bellare, V. K. Kadambar, P. Bollella, E. Katz and A. Melman, Chem. Commun., 2019, 55, 7856 DOI: 10.1039/C9CC03467F

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