Synthesis and characterization of metallapentalenoxazetes by the [2+2] cycloaddition of metallapentalynes with nitrosoarenes

Zhihong Deng; Congqing Zhu; Yuhui Hua; Guomei He; Ying Guo; Ruqiang Lu; Xiaoyu Cao; Jiangxi Chen; Haiping Xia

doi:10.1039/C9CC02594D

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Synthesis and characterization of metallapentalenoxazetes by the [2+2] cycloaddition of metallapentalynes with nitrosoarenes†

Zhihong Deng,

^a Congqing Zhu,^b Yuhui Hua,^b Guomei He,

^a Ying Guo,^b Ruqiang Lu,^b Xiaoyu Cao,

^b Jiangxi Chen

*^a and Haiping Xia

*^bc

Author affiliations

* Corresponding authors

^a Department of Materials Science and Engineering, College of Materials, Xiamen University, Xiamen 361005, People's Republic of China
E-mail: chenjx@xmu.edu.cn

^b College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, People's Republic of China
E-mail: hpxia@xmu.edu.cn

^c Department of Chemistry, Shenzhen Grubbs Institute, Southern University of Science and Technology, Shenzhen 518055, People's Republic of China

Abstract

Cycloaddition reactions of carbynes in metallacycles with π-bond substrates have been rarely reported. We report the first [2+2] cycloaddition of metallapentalynes with nitrosoarenes to obtain the first metallapentalenoxazetes, and their photophysical and electrochemical properties were studied by UV-Vis spectroscopy and cyclic voltammetry with the help of theoretical calculations.

Download options Please wait...

Supplementary files

Article information

DOI: https://doi.org/10.1039/C9CC02594D
Article type: Communication
Submitted: 03 Apr 2019
Accepted: 03 May 2019
First published: 04 May 2019

Download Citation

Chem. Commun., 2019,55, 6237-6240

Permissions

Request permissions

Synthesis and characterization of metallapentalenoxazetes by the [2+2] cycloaddition of metallapentalynes with nitrosoarenes

Z. Deng, C. Zhu, Y. Hua, G. He, Y. Guo, R. Lu, X. Cao, J. Chen and H. Xia, Chem. Commun., 2019, 55, 6237 DOI: 10.1039/C9CC02594D

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Chemical Communications

Synthesis and characterization of metallapentalenoxazetes by the [2+2] cycloaddition of metallapentalynes with nitrosoarenes†

Abstract

Supplementary files

Article information

Download Citation

Permissions

Synthesis and characterization of metallapentalenoxazetes by the [2+2] cycloaddition of metallapentalynes with nitrosoarenes

Social activity

Search articles by author

Spotlight

Advertisements