SCHEDULED MAINTENANCE
Application of the covalent bond classification to the compounds [M2(η5-C5H5)2(μ-H)(μ-PCy2)(CO)2] (M = Mo, W) identifies the compounds as having two M–M bonds and a 2 electron 3 centre (2e–3c) bond incorporating the bridging hydrogen, in accord with density functional calculations, and assigns their class as ML4X4.
![Graphical abstract: Comment on “Hydride, gold(i) and related derivatives of the unsaturated ditungsten anion [W2Cp2(μ-PCy2)(μ-CO)2]−” by M. A. Ruiz et al., Dalton Trans., 2014, 43, 16044](/en/Image/Get?imageInfo.ImageType=GA&imageInfo.ImageIdentifier.ManuscriptID=C8DT00044A&imageInfo.ImageIdentifier.Year=2018)
M. L. H. Green, Dalton Trans., 2018, 47, 6628 DOI: 10.1039/C8DT00044A
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