Issue 26, 2017
From the journal:

RSC Advances

Palladium catalyzed Suzuki cross-coupling of benzyltrimethylammonium salts via C–N bond cleavage†

Tao Wang, ORCID logo ab   Shuwu Yang,b   Silin Xu,b   Chunyu Han,b   Ge Guob  and  Junfeng Zhao*ab  

* Corresponding authors

a National Research Center for Carbohydrate Synthesis, Key Laboratory of Chemical Biology, Jiangxi Province, China

b College of Chemistry & Chemical Engineering, Jiangxi Normal University, 99, Ziyang Road, Nanchang, Jiangxi, P. R. China
E-mail: zhaojf@jxnu.edu.cn

Abstract

A palladium catalyzed Suzuki cross-coupling for construction of Csp3–Csp2 bond via Csp3–N bond activation of benzyltrimethyl-ammonium salt is described. This reaction not only offered a highly efficient approach to diarylmethanes but also paved the way for the application of benzyltrimethylammonium salts in the palladium catalyzed cross coupling reactions.

Graphical abstract: Palladium catalyzed Suzuki cross-coupling of benzyltrimethylammonium salts via C–N bond cleavage

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Article information

DOI
https://doi.org/10.1039/C7RA02549A
Article type
Paper
Submitted
01 Mar 2017
Accepted
02 Mar 2017
First published
09 Mar 2017
This article is Open Access
Creative Commons BY-NC license

RSC Adv., 2017,7, 15805-15808

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Palladium catalyzed Suzuki cross-coupling of benzyltrimethylammonium salts via C–N bond cleavage

T. Wang, S. Yang, S. Xu, C. Han, G. Guo and J. Zhao, RSC Adv., 2017, 7, 15805 DOI: 10.1039/C7RA02549A

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