Issue 7, 2018
From the journal:

Organic & Biomolecular Chemistry

Deoxygenation of sulphoxides to sulphides with trichlorophosphane†

Xia Zhao, ORCID logo *a   Xiancai Zheng,a   Bo Yang,a   Jianqiao Shenga  and  Kui Lu ORCID logo b  

* Corresponding authors

a College of Chemistry, Tianjin Key Laboratory of Structure and Performance for Functional Molecules, Key laboratory of Inorganic–organic Hybrid Functional Material Chemistry, Ministry of Education, Tianjin Normal University, Tianjin 300387, China
E-mail: hxxyzhx@mail.tjnu.edu.cn

b College of Biotechnology, Tianjin University of Science & Technology, Tianjin 300457, China

Abstract

An efficient route to deoxygenation of sulphoxides to sulphides with PCl3 under mild reaction condition was developed. PCl3 was used as a reducing agent for the first time to convert sulphoxides to sulphides. The mild conditions, use of cheap and readily available reagent, and broad substrate scope render it a useful strategy for preparing sulphides.

Graphical abstract: Deoxygenation of sulphoxides to sulphides with trichlorophosphane

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Article information

DOI
https://doi.org/10.1039/C7OB02834B
Article type
Paper
Submitted
18 Nov 2017
Accepted
25 Jan 2018
First published
25 Jan 2018

Org. Biomol. Chem., 2018,16, 1200-1204

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Deoxygenation of sulphoxides to sulphides with trichlorophosphane

X. Zhao, X. Zheng, B. Yang, J. Sheng and K. Lu, Org. Biomol. Chem., 2018, 16, 1200 DOI: 10.1039/C7OB02834B

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