Issue 96, 2017

From helix to helical pores: solid-state crystalline conversions triggered by gas–solid reactions

Abstract

Two one-dimensional (1D) helical coordination polymers, CuBIm–Cl and CuBIm–Br (BIm = 1,2-bis((5H-imidazol-4-yl)-methylene)hydrazine), are constructed from Cu2+ ions, halides and mono-deprotonated BIm. Solid-state crystalline conversions of CuBIm–Cl and CuBIm–Br to a gyroidal metal–organic framework (MOF) STU-3 which is composed of Cu ions and Bim ligands are observed through a gas–solid reaction, where the gas is methylamine.

Graphical abstract: From helix to helical pores: solid-state crystalline conversions triggered by gas–solid reactions

Supplementary files

Article information

Article type
Communication
Submitted
27 Sep 2017
Accepted
08 Nov 2017
First published
08 Nov 2017

Chem. Commun., 2017,53, 12950-12953

From helix to helical pores: solid-state crystalline conversions triggered by gas–solid reactions

J. Liu, J. Du, Y. Wu, Y. Zhao, X. Zhou and D. Li, Chem. Commun., 2017, 53, 12950 DOI: 10.1039/C7CC07510C

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