Abstract
Although boron-based fluorophores incorporating nitrogenous chelating ligands have received much attention, there has been little work on examples of boron-salphen and azine derivatives. In this report, we present several it expanded boron salphen type complexes, incorporating both bis(2-hydroxy-naphthaldehyde)azine as well as ortho, meta and para variants of the analogous 2-hydroxynaphthalde-hyde salphen compounds. For the azine, we observed only the formation of a single BF2 adduct, while for the naphth-phen compounds dimeric BF2 binding was observed. All new compounds were fully characterized via X-ray diffraction, and both DFT. and TDDFT. studies were carried out to probe the electronic structures of these fluorophores
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Electronic supplementary information (ESI) available: Spectroscopic, and crystallographic data for compounds. CCDC 1523987-1523991 for 1-5. For ESI and crystallographic data in CIF. or other electronic format see DOI: 10.1039/C6pp00479b
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Crandall, L.A., Dawadi, M.B., Burrell, T. et al. Structure and electronics in dimeric boron π expanded azine and salphen complexes. Photochem Photobiol Sci 16, 627–632 (2017). https://doi.org/10.1039/c6pp00479b
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DOI: https://doi.org/10.1039/c6pp00479b