Issue 129, 2015
From the journal:

RSC Advances

Nitroalkenes as surrogates for cyanomethylium species in a one-pot synthesis of non-symmetric diarylacetonitriles†

Alexander V. Aksenov,*a   Nicolai A. Aksenov,a   Zarema V. Dzhandigova,a   Dmitrii A. Aksenova  and  Michael Rubin*ab  

* Corresponding authors

a Department of Chemistry, North Caucasus Federal University, 1a Pushkin St., Stavropol 355009, Russian Federation
E-mail: alexaks05@rambler.ru
Tel: +7 918 743 0255

b Department of Chemistry, University of Kansas, 1251 Wescoe Hall Dr., Lawrence, KS 66045-7582, USA
E-mail: mrubin@ku.edu
Fax: +1 785 864 5396
Tel: +1 785 864 5071

Abstract

Nitroalkenes were used as synthetic equivalents of the cyanomethylium cation in a modular, one-pot synthesis of 2-(3-indolyl)acetonitriles and 2,2-diarylacetonitriles involving electrophilic functionalization of aromatic and heteroaromatic C–H bond.

Graphical abstract: Nitroalkenes as surrogates for cyanomethylium species in a one-pot synthesis of non-symmetric diarylacetonitriles

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Article information

DOI
https://doi.org/10.1039/C5RA20953F
Article type
Paper
Submitted
09 Oct 2015
Accepted
30 Nov 2015
First published
02 Dec 2015

RSC Adv., 2015,5, 106492-106497

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Nitroalkenes as surrogates for cyanomethylium species in a one-pot synthesis of non-symmetric diarylacetonitriles

A. V. Aksenov, N. A. Aksenov, Z. V. Dzhandigova, D. A. Aksenov and M. Rubin, RSC Adv., 2015, 5, 106492 DOI: 10.1039/C5RA20953F

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